Mechanistic Investigation of Enediyne-Connected Amino Ester Rearrangement. Theoretical Rationale for the Exclusive Preference for 1,6-or 1,5-Hydrogen Atom Transfer Depending on the Substrate. A Potential Route to Chiral Naphthoazepines

Mechanistic Investigation of Enediyne-Connected Amino Ester Rearrangement. Theoretical Rationale for the Exclusive Preference for 1,6-or 1,5-Hydrogen Atom Transfer Depending on the Substrate. A Potential Route to Chiral Naphthoazepines

Damien Campolo, Anouk Gaudel-Siri, Shovan Mondal, Didier Siri, Eric Besson, Nicolas Vanthuyne, Malek Nechab, Michele P. Bertrand
Journal of Organic Chemistry, 77 2773-2783 (2012)