Proteasome Inhibiting Beta-Lactam Produrgs Useful for the Treatment of Cancer and Nurodegenerative Disorders
Unraveling the reaction mechanism of AlCl3 Lewis acid catalyzed acylation reaction of pyrene from the perspective of the molecular electron density theory
Development of an Efficient Thionolactone for Radical Ring-Opening Polymerization by a Combined Theoretical/Experimental Approach
The IMSCal approach to determine collision cross section of multiply charged anions in traveling wave ion mobility spectrometry
Novel Sterically Crowded and Conformationally Constrained α-Aminophosphonates with a Near-Neutral pKa as Highly Accurate 31P NMR pH Probes. Application to Subtle pH Gradients Determination in Dictyostelium discoideum Cells
Switching from (R)- to (S)-selective chemoenzymatic DKR of amines involving sulfanyl radical-mediated racemization
Diasteromeric Effect on the Homolysis of the C-ON Bond in Alkoxyamines: A DFT Investigation of 1,3-Diphenylbutyl-TEMPO
Spin-Trapping Evidence for the Formation of Alkyl, Alkoxyl, and Alkylperoxyl Radicals in the Reactions of Dialkylzincs with Oxygen
Mechanistic Investigation of Enediyne-Connected Amino Ester Rearrangement. Theoretical Rationale for the Exclusive Preference for 1,6-or 1,5-Hydrogen Atom Transfer Depending on the Substrate. A Potential Route to Chiral Naphthoazepines
Analysis of the physical contributions to magnetic couplings in broken symmetry density functional theory approach
Assessing the accuracy of a QM/MM//MD combined protocol to compute spectromagnetic properties of polyfunctional nitroxides in solution
Chemically Triggered C-ON Bond Homolysis in Alkoxyamines. Part 2: DFT Investigation and Application of the pH Effect on NMP
Aminomethylation of Michael Acceptors: Complementary Radical and Polar Approaches Mediated by Dialkylzincs
EPR Investigation of Zinc/Iodine Exchange between Propargyl Iodides and Diethylzinc: Detection of Propargyl Radical by Spin Trapping
Theoretical Support for the Involvement of a Radical Pathway in the Formation of Allenylzincs from Propargyl Iodides and Dialkylzincs: Influence of Zinc Coordination
Theoretical Study To Explain How Chirality Is Stored and Evolves throughout the Radical Cascade Rearrangement of Enyne-allenes
Synthesis and Spin-Trapping Properties of a Trifluoromethyl Analogue of DMPO: 5-Methyl-5-trifluoromethyl-1-pyrroline N-Oxide (5-TFDMPO)
Spin Exchange Monitoring of the Strong Positive Homotropic Allosteric Binding of a Tetraradical by a Synthetic Receptor in Water
Theoretical investigation of the reaction of dialkylzincs with alpha-alkoxycarbonyl radicals. Evaluation of alpha-bromoacrylates as radical acceptors in radical-polar crossover processes
On the structure-control relationship of amide-functionalized SG1-based alkoxyamines for nitroxide-mediated polymerization and conjugation
Computational Studies on Intramolecular Cycloadditions of Azidoenynes and Azidobutenenitriles to Give 6H-Pyrrolo[1,2-c][1,2,3]triazoles and 5H-Pyrrolo[1,2-d]tetrazoles
Palladium Tandem Catalysis in the Atropodiastereoselective Synthesis of Indenes Bearing Central and Axial Chirality
Tailoring of Polarizing Agents in the bTurea Series for Cross-Effect Dynamic Nuclear Polarization in Aqueous Media
New Amino-Acid-Based beta-Phosphorylated Nitroxides for Probing Acidic pH in Biological Systems by EPR Spectroscopy
Cycloaddition of sulfonyl azides and cyanogen azide to enamines. Quantum-chemical calculations concerning the spontaneous rearrangement of the adduct into ring-contracted amidines
Synthesis and properties of a series of beta-cyclodextrin/nitrone spin traps for improved superoxide detection
Alkylperoxyl spin adducts of pyrroline-N-oxide spin traps: Experimental and theoretical CASSCF study of the unimolecular decomposition in organic solvent, potential applications in water
Chiral Fidelity in the Diastereoselective and Enantiospecific Synthesis of Indenes from Axially Chiral Benzylidene Cyclanes
A comprehensive kinetic study of the conventional free-radical polymerization of seven-membered cyclic ketene acetals
Chameleonic Dye Adapts to Various Environments Shining on Macrocycles or Peptide and Polysaccharide Aggregates
Radical Copolymerization of Vinyl Ethers and Cyclic Ketene Acetals as a Versatile Platform to Design Functional Polyesters
Reactivity of benzylidene and alkylidenemalonates in radical addition mediated with dialkylzincs - An intriguing story
Simulation of the Degradation of Cyclic Ketene Acetal and Vinyl-Based Copolymers Synthesized via a Radical Process: Influence of the Reactivity Ratios on the Degradability Properties
TinyPols: a family of water-soluble binitroxides tailored for dynamic nuclear polarization enhanced NMR spectroscopy at 18.8 and 21.1 T
Intermolecular Addition of Carbon-Centered Radicals to Ynamides. A Regio- and Stereoselective Route to Persubstituted alpha-lodo-enamides
Structure and Spectromagnetic Properties of the Superoxide Radical Adduct of DMPO in Water: Elucidation by Theoretical Investigations
Scope and limitations of the nitroxide-mediated radical ring-opening polymerization of cyclic ketene acetals
N-Acetoxy-phthalimide (NAPI) as a new H-abstracting agent at high temperature: application to the melt functionalization of polyethylene
Melt radical grafting of diethylmaleate and maleic anhydride onto oligoamide-11 (OA11) and polyamide-11 (PA11) in presence of acyloxyimide derivatives: Toward the compatibilization of PA11/EVOH blends
Collision-induced dissociation of stable nitroxides: A combined tandem mass spectrometry and computational study of TEMPO center dot and SG1(center dot)
Acyloxyimide derivatives as efficient promoters of polyolefin C-H functionalization: application in the melt grafting of maleic anhydride onto polyethylene
Open and Closed Radicals: Local Geometry around Unpaired Electrons Governs Magic-Angle Spinning Dynamic Nuclear Polarization Performance
Enthalpy of Combustion on n-Alkanes. Quantum Chemical Calculations up to n-C60H122 and Power Law Distributions
Supramolecular Encapsulation and Bioactivity Modulation of a Halonium Ion by Cucurbit[n]uril (n=7, 8)
