Mechanistic Investigation of Enediyne-Connected Amino Ester Rearrangement. Theoretical Rationale for the Exclusive Preference for 1,6-or 1,5-Hydrogen Atom Transfer Depending on the Substrate. A Potential Route to Chiral Naphthoazepines
Arylsulfanyl radical lifetime in nanostructured silica: dramatic effect of the organic monolayer structure
Theoretical investigation of the reaction of dialkylzincs with alpha-alkoxycarbonyl radicals. Evaluation of alpha-bromoacrylates as radical acceptors in radical-polar crossover processes
Design of Wall-Functionalized Hybrid Silicas Containing Diazene Radical Precursors. EPR Investigation of Their Photolysis and Thermolysis
Silica materials with wall-embedded nitroxides provide efficient polarization matrices for dynamic nuclear polarization NMR
Solid state generation of phenoxyl radicals through beta-fragmentation from specifically designed diazenes. An ESR investigation
Diazene-Functionalized Lamellar Materials as Nanobuilding Blocks: Application as Light-Sensitive Fillers to Initiate Radical Photopolymerizations
Investigating Unusual Organic Functional Groups to Engineer the Surface Chemistry of Mesoporous Silica to Tune CO2-Surface Interactions
Evidence for the contribution of degenerate hydrogen atom transport to the persistence of sulfanyl radicals anchored to nanostructured hybrid materials
Investigating the efficiency of silica materials with wall-embedded nitroxide radicals for dynamic nuclear polarisation NMR
An efficient and recyclable hybrid nanocatalyst to promote enantioselective radical cascade rearrangements of enediynes
Modulating lifetimes and relaxation times of phenoxyl radicals through their incorporation into different hybrid nanostructures
Embedding cyclic nitrone in mesoporous silica particles for EPR spin trapping of superoxide and other radicals
Monitoring Crystallization Processes in Confined Porous Materials by Dynamic Nuclear Polarization Solid-State Nuclear Magnetic Resonance
Probing the efficiency of thermal and photochemical bond homolysis in functionalized nanostructured SBA-15 silicas
Nanostructured Silicas, a Platform for the Observation of Transient Radicals: Application to Sulfinyl Radicals
