Switching from (R)- to (S)-selective chemoenzymatic DKR of amines involving sulfanyl radical-mediated racemization
Spin-Trapping Evidence for the Formation of Alkyl, Alkoxyl, and Alkylperoxyl Radicals in the Reactions of Dialkylzincs with Oxygen
N-Octanoyldimethylglycine Trifluoroethyl Ester, an Acyl Donor Leading to Highly Enantioselective Protease-Catalysed Kinetic Resolution of Amines
Novozym 435-catalyzed synthesis of polyetheramides from amino-esters, or diesters and diamines built on ethylene- and diethylene- glycol moieties
Kinetic Studies on the Formation of Sulfonyl Radicals and Their Addition to Carbon-Carbon Multiple Bonds
Mechanistic Investigation of Enediyne-Connected Amino Ester Rearrangement. Theoretical Rationale for the Exclusive Preference for 1,6-or 1,5-Hydrogen Atom Transfer Depending on the Substrate. A Potential Route to Chiral Naphthoazepines
Aminomethylation of Michael Acceptors: Complementary Radical and Polar Approaches Mediated by Dialkylzincs
Speeding-up enzyme-catalyzed synthesis of polyamides using omega-amino-alpha-alkoxy-acetate as monomer
Theoretical Support for the Involvement of a Radical Pathway in the Formation of Allenylzincs from Propargyl Iodides and Dialkylzincs: Influence of Zinc Coordination
Photoactivated cyclization of aryl-containing enediynes coated gold nanoparticles: Enhancement of the DNA cleavage ability of enediynes
Theoretical Study To Explain How Chirality Is Stored and Evolves throughout the Radical Cascade Rearrangement of Enyne-allenes
Arylsulfanyl radical lifetime in nanostructured silica: dramatic effect of the organic monolayer structure
Theoretical investigation of the reaction of dialkylzincs with alpha-alkoxycarbonyl radicals. Evaluation of alpha-bromoacrylates as radical acceptors in radical-polar crossover processes
Organocopper-Triggered Cyclisation of Conjugated Diene-ynes: Diastereo- and Enantioselective Synthesis of Indenes
Design of Wall-Functionalized Hybrid Silicas Containing Diazene Radical Precursors. EPR Investigation of Their Photolysis and Thermolysis
Palladium Tandem Catalysis in the Atropodiastereoselective Synthesis of Indenes Bearing Central and Axial Chirality
Solid state generation of phenoxyl radicals through beta-fragmentation from specifically designed diazenes. An ESR investigation
Diazene-Functionalized Lamellar Materials as Nanobuilding Blocks: Application as Light-Sensitive Fillers to Initiate Radical Photopolymerizations
Evidence for the contribution of degenerate hydrogen atom transport to the persistence of sulfanyl radicals anchored to nanostructured hybrid materials
Chiral Fidelity in the Diastereoselective and Enantiospecific Synthesis of Indenes from Axially Chiral Benzylidene Cyclanes
Reactivity of benzylidene and alkylidenemalonates in radical addition mediated with dialkylzincs – An intriguing story
Intermolecular Addition of Carbon-Centered Radicals to Ynamides. A Regio- and Stereoselective Route to Persubstituted alpha-lodo-enamides
Unprecedented Noncatalyzal anti-Carbozincation of Diethyl Acetylenedicarboxylate through Alkylzinc Group Radical Transfer
An efficient and recyclable hybrid nanocatalyst to promote enantioselective radical cascade rearrangements of enediynes
Synthesis of tetrahydropyrans and related heterocycles via prins cyclization; extension to aza-prins cyclization
Copper Carbenoid, Reactant and Catalyst for One-Pot Diazo Ester Coupling Cascade Rearrangement of Enediynes: Formation of Two Contiguous Tetrasubstituted Stereocenters
Cooperative Use of VCD and XRD for the Determination of Tetrahydrobenzoisoquinolines Absolute Configuration: A Reliable Proof of Memory of Chirality and Retention of Configuration in Enediyne Rearrangements
Enantioselective Synthesis of Carbocycles and Heterocycles by Radical/Polar and Polar/Radical Cascades
Double Transfer of Chirality in Organocopper-Mediated bis(Alkylating) Cycloisomerization of Enediynes
A Flexible, Stereoselective Dimethylzinc-Mediated Radical-Anionic Cascade: Dramatic Influence of Additional Lewis Acids
Access to original spirocyclic derivatives via inter- or intramolecular reaction mediated by manganese(III) acetate
Nanostructured Silicas, a Platform for the Observation of Transient Radicals: Application to Sulfinyl Radicals
