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Publication authors: Michele P. Bertrand

alpha-Haloenamides: Synthesis and Subsequent Transformations

Switching from (R)- to (S)-selective chemoenzymatic DKR of amines involving sulfanyl radical-mediated racemization

Memory of Chirality in Cascade Rearrangements of Enediynes

Spin-Trapping Evidence for the Formation of Alkyl, Alkoxyl, and Alkylperoxyl Radicals in the Reactions of Dialkylzincs with Oxygen

Enzyme-triggered Radical Reactions: Another Approach For Tin-free Radical Chemistry

N-Octanoyldimethylglycine Trifluoroethyl Ester, an Acyl Donor Leading to Highly Enantioselective Protease-Catalysed Kinetic Resolution of Amines

Novozym 435-catalyzed synthesis of polyetheramides from amino-esters, or diesters and diamines built on ethylene- and diethylene- glycol moieties

CAL-B catalyzed synthesis of chiral polyamides

Kinetic Studies on the Formation of Sulfonyl Radicals and Their Addition to Carbon-Carbon Multiple Bonds

Mechanistic Investigation of Enediyne-Connected Amino Ester Rearrangement. Theoretical Rationale for the Exclusive Preference for 1,6-or 1,5-Hydrogen Atom Transfer Depending on the Substrate. A Potential Route to Chiral Naphthoazepines

Aminomethylation of Michael Acceptors: Complementary Radical and Polar Approaches Mediated by Dialkylzincs

Axial-to-central chirality transfer in cyclization processes

Speeding-up enzyme-catalyzed synthesis of polyamides using omega-amino-alpha-alkoxy-acetate as monomer

Theoretical Support for the Involvement of a Radical Pathway in the Formation of Allenylzincs from Propargyl Iodides and Dialkylzincs: Influence of Zinc Coordination

Photoactivated cyclization of aryl-containing enediynes coated gold nanoparticles: Enhancement of the DNA cleavage ability of enediynes

New Thiols for Photoinitiator-Free Thiol-Acrylate Polymerization

Theoretical Study To Explain How Chirality Is Stored and Evolves throughout the Radical Cascade Rearrangement of Enyne-allenes

Arylsulfanyl radical lifetime in nanostructured silica: dramatic effect of the organic monolayer structure

Theoretical investigation of the reaction of dialkylzincs with alpha-alkoxycarbonyl radicals. Evaluation of alpha-bromoacrylates as radical acceptors in radical-polar crossover processes

Organocopper-Triggered Cyclisation of Conjugated Diene-ynes: Diastereo- and Enantioselective Synthesis of Indenes

Design of Wall-Functionalized Hybrid Silicas Containing Diazene Radical Precursors. EPR Investigation of Their Photolysis and Thermolysis

Palladium Tandem Catalysis in the Atropodiastereoselective Synthesis of Indenes Bearing Central and Axial Chirality

Solid state generation of phenoxyl radicals through beta-fragmentation from specifically designed diazenes. An ESR investigation

Diazene-Functionalized Lamellar Materials as Nanobuilding Blocks: Application as Light-Sensitive Fillers to Initiate Radical Photopolymerizations

Evidence for the contribution of degenerate hydrogen atom transport to the persistence of sulfanyl radicals anchored to nanostructured hybrid materials

Chiral Fidelity in the Diastereoselective and Enantiospecific Synthesis of Indenes from Axially Chiral Benzylidene Cyclanes

Reactivity of benzylidene and alkylidenemalonates in radical addition mediated with dialkylzincs – An intriguing story

Organocopper triggered cyclization of conjugated dienynes via tandem S(N)2/Alder-ene reaction

Intermolecular Addition of Carbon-Centered Radicals to Ynamides. A Regio- and Stereoselective Route to Persubstituted alpha-lodo-enamides

Unprecedented Noncatalyzal anti-Carbozincation of Diethyl Acetylenedicarboxylate through Alkylzinc Group Radical Transfer

Straightforward Access to alpha-Methylamines through Cross-Metathesis

An efficient and recyclable hybrid nanocatalyst to promote enantioselective radical cascade rearrangements of enediynes

Synthesis of tetrahydropyrans and related heterocycles via prins cyclization; extension to aza-prins cyclization

Copper Carbenoid, Reactant and Catalyst for One-Pot Diazo Ester Coupling Cascade Rearrangement of Enediynes: Formation of Two Contiguous Tetrasubstituted Stereocenters

Chemoenzymatic Dynamic Kinetic Resolution of Primary Amines Catalyzed by CAL-B at 38-40 degrees C

One-pot Crabbe homologation-radical cascade cyclisation with memory of chirality

Cooperative Use of VCD and XRD for the Determination of Tetrahydrobenzoisoquinolines Absolute Configuration: A Reliable Proof of Memory of Chirality and Retention of Configuration in Enediyne Rearrangements

Enantioselective Synthesis of Carbocycles and Heterocycles by Radical/Polar and Polar/Radical Cascades

Intramolecular Trapping of Allenylzincs by Carbonyl Groups

Double Transfer of Chirality in Organocopper-Mediated bis(Alkylating) Cycloisomerization of Enediynes

A Flexible, Stereoselective Dimethylzinc-Mediated Radical-Anionic Cascade: Dramatic Influence of Additional Lewis Acids

Access to original spirocyclic derivatives via inter- or intramolecular reaction mediated by manganese(III) acetate

Nanostructured Silicas, a Platform for the Observation of Transient Radicals: Application to Sulfinyl Radicals

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